Title

Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses.

Document Type

Article

Publication Date

4-11-2016

Abstract

The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.

Publication Title

Dalton transactions

Comments

This article was published in Dalton Transactions, 2016.

The published version is available at http://dx.doi.org/10.1039/C5DT04760A

Copyright © 2016 Royal Society of Chemistry

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